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• W2949273658 abstract "A perfluoroalkylsulfonyl fluoride-mediated abnormal Beckmann rearrangement is reported which transforms steroid 17-oximes to the corresponding alkene nitriles regioselectively in good yields. This reaction is rapid (completes in 25 min), mild (proceeds at room temperature) and, most importantly, tolerates various acid-labile functional groups, such as methoxymethyl (MOM), ketal, and methyl enol ether, providing access to molecules that would be difficult to synthesize using existing methods." @default.
• W2949273658 created "2019-06-27" @default.
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• W2949273658 date "2014-07-01" @default.
• W2949273658 modified "2023-09-26" @default.
• W2949273658 title "Perfluoroalkylsulfonyl fluoride-mediated abnormal Beckmann rearrangement of steroid 17-oximes with acid-labile groups" @default.
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• W2949273658 doi "https://doi.org/10.1016/j.tetlet.2014.06.005" @default.
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