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• W2949273879 abstract "Abstract The nomenclature which Alfred Werner introduced in coordination (complex) chemistry is imposed on cluster compounds, especially on those which contain endohedral atoms to enhance the electron count for intra‐cluster bonding. Formulae are written in a way that, beginning with the central atom, the sequence of coordination spheres is illustrated. For example, the iodide so far mostly written as Cs 4 Pr 6 I 13 C 2 , a formula which tells nothing about the structure, is then rewritten as follows, {(C 2 )Pr 6 }I 13 Cs 4 . Cs 2 Mo 6 Cl 14 would be [{□Mo 6 }Cl 8 i Cl 6 a ]Cs 2 . Square brackets, [ ], are used for an anionic or cationic complex which ideally exists in solution, braces, { }, are reserved for clusters with intra‐cluster metal‐metal and/or metal‐interstitial bonding. Whenever feasible other nomenclatures are included, for example Niggli 's way to hint at connections as in {(C 2 )Dy 4/1 Dy 2/2 } 2 {ODy 2/2 Dy 2/2 } 2 I 24 , or the Schäfer–Schnering nomenclature for ligand functionalities as in {Mo 6 }Cl 8 i Cl 2 a Cl 4/2 a‐a . This way of considering cluster complexes as anti‐Werner complexes is especially useful when coordination numbers and polyhedra of endohedral atoms are considered in a systematic way." @default.
• W2949273879 created "2019-06-27" @default.
• W2949273879 creator A5068165268 @default.
• W2949273879 date "2008-11-17" @default.
• W2949273879 modified "2023-10-18" @default.
• W2949273879 title "Cluster Complexes as<i>anti-Werner</i>Complexes" @default.
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• W2949273879 doi "https://doi.org/10.1002/zaac.200800375" @default.
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