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• W2949274671 abstract "Abstract Biruthenocene was prepared in high yield by a radical reaction of ruthenocene in sulfuric acid at 80°C. Biruthenocene reacts with FeIII salts, HX (X; Br, Cl), and NH4PF6, giving diamagnetic biruthenoceniumX+PF−6 salts. Based on the 13C-Cp-MAS, 13C-, and 1H-NMR spectroscopic studies of the salts, it was found that the structure is expressed as [RuIICp(C5H4)(C5H4)(C5H4)CpRuIVX]+PF−6 in solid, and there is a rapid intramolecular electron transmission between the two Ru atoms, [RuIICp*(C5H4)(C5H4)CpRuIVX]+ ⇌ [XRuIVCp*(C5H4)(C5H4)CpRuII]+, in acetonitrile." @default.
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• W2949274671 date "1990-12-01" @default.
• W2949274671 modified "2023-09-24" @default.
• W2949274671 title "A novel method for the synthesis of biruthenocene and an NMR spectroscopic study of the products of the reaction of biruthenocene with Lewis acids" @default.
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• W2949274671 doi "https://doi.org/10.1016/0022-328x(90)85494-j" @default.
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