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- W2949278317 abstract "The synthesis of the first known mercaptosulfonium salts H3S2+AsF6-, H3S2+SbF6-, and D3S2+AsF6- is reported. The salts were prepared by protonation of H2S2 in the superacidic systems HF−AsF5, HF−SbF5, and DF−AsF5, respectively. The solids decomposed at 213 K under formation of sulfur and H3S+ salts. The mercaptosulfonium salts are characterized by vibrational spectra. An ab initio and a general valence force field were calculated for the H3S2+ cation. The calculations give a conformation with the S−H bond antiperiplanar to the lone pair of SH2+." @default.
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- W2949278317 date "1996-01-01" @default.
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- W2949278317 title "Synthesis and Characterization of the Mercaptosulfonium Cation, HSSH<sub>2</sub><sup>+</sup>" @default.
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- W2949278317 doi "https://doi.org/10.1021/ic951599k" @default.
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