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- W2949279712 abstract "Abstract Polyfluoroalkylsulfanyl-substituted tetrathiafulvalene derivatives have been synthesised via self- or cross-coupling of suitable 2-(thi)oxo-1, 3-dithioles. Key intermediates are 4,5-bis(polyfluoroalkyl-sulfanyl)-2-thioxo-1,3-dithioles, formed from reaction between 2-(F-alkyl)-1-iodoethanes C n F 2 n +1 −C 2 H 4 I ( n = 6,8) and bis(tetraethylammonium) bis(1,3-dithiole-2-thione-4,5-dithiolato)zincate, and 4-[2′-(F-hexyl-ethylsulfanyl]-5-methylsulfanyl-2-thioxo-1, 3-dithiole. Self- and cross-coupling products are formed in fair to very good yields by using tri-isopropylphosphite, instead of the more usual triethyl or trimethylphosphite. All of these new TTF-derivatives exhibit quasi reversible voltammograms. Cation radical salts have been obtained mainly from one of these derivatives, whose anodic oxidation, in the presence of tetrabutylammonium hexafluorophosphate or perchlorate, allows isolation of very thin ‘hair-like’ threads." @default.
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- W2949279712 date "2010-06-22" @default.
- W2949279712 modified "2023-10-02" @default.
- W2949279712 title "ChemInform Abstract: Polyfluoroalkylsulfanyl-Substituted Tetrathiafulvalene Derivatives: Synthesis, Electrochemical Properties, and Derived Cation Radical Salts." @default.
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- W2949279712 doi "https://doi.org/10.1002/chin.199819126" @default.
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