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• W2949285906 abstract "A new phosphate crystal CsMg2P3O10 was grown by molten salt method. The single-crystal X-ray diffraction analysis reveals that this compound crystallizes in orthorhombic space group Pbcn (No.60) with unit cell parameters a = 7.8757(8) Å, b = 8.6902(9) Å and c = 13.7235(14) Å, V = 939.26(17) Å3. In the structure, the basic building units are the [P3O10]5- trimers consisted of three PO4 tetrahedra shared the corner oxygen atoms, and the [Mg2O8] dimers composed of two MgO5 hexahedrons linked through edge-sharing. The structure exhibits a novel three-dimensional network, constructed by the [Mg2O8] dimers and [P3O10]5- trimers, where the Cs+ ions reside in the cavities. Furthermore, some related tests and first-principle calculations were employed for the compound characterization." @default.
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• W2949285906 date "2019-08-01" @default.
• W2949285906 modified "2023-09-23" @default.
• W2949285906 title "Synthesis, structure and characterization of a new triphosphate: CsMg2P3O10" @default.
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• W2949285906 doi "https://doi.org/10.1016/j.solidstatesciences.2019.06.006" @default.
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