FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949304880> ?p ?o ?g. }

• W2949304880 endingPage "2792" @default.
• W2949304880 startingPage "2780" @default.
• W2949304880 abstract "The formation of quaternary rare-earth (RE) germanides containing transition metals (M’s) from groups 6 to 10 was investigated through arc-melting and annealing reactions at 800 °C; about 50 new compounds were obtained. These include several new series of quaternary germanides RE4M2InGe4 (M = Fe, Co, Ru, Rh, Ir), previously known only for M = Mn and Ni; additional members of RE4Ni2InGe4 extended to other RE substituents; and a different but closely related series RE4RhInGe4. Detailed crystal structures were determined by single-crystal X-ray diffraction studies for 20 compounds. Monoclinic structures in space group C2/m are adopted by RE4M2InGe4 (Ho4Ni2InGe4-type, a = 15.1–16.5 Å, b = 4.1–4.4 Å, c = 6.9–7.3 Å, β = 106.2–108.6°) and RE4RhInGe4 (own type, a = 20.0–20.2 Å, b = 4.2–4.3 Å, c = 10.1–10.2 Å, β = 105.0–105.3°). Both structures contain frameworks built from MGe4 tetrahedra, InGe4 square planes, and Ge2 dimers, delimiting tunnels occupied by RE atoms. These structures can also be derived by cutting slabs along different directions from the more symmetrical RE2InGe2 structure. Although the Ge2 dimers are relatively invariant, the InGe4 square planes can undergo distortion to form two sets of short versus long In–Ge distances. This distortion results from a competition between M–Ge bonding in the MGe4 tetrahedra and In–Ge bonding in the InGe4 square planes." @default.
• W2949304880 created "2019-06-27" @default.
• W2949304880 creator A5017376122 @default.
• W2949304880 creator A5047592331 @default.
• W2949304880 creator A5074696645 @default.
• W2949304880 date "2015-03-02" @default.
• W2949304880 modified "2023-10-16" @default.
• W2949304880 title "Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE₄M₂InGe₄ (M = Fe, Co, Ni, Ru, Rh, Ir) and RE₄RhInGe₄ Derived from Excision of Slabs in RE₂InGe₂" @default.
• W2949304880 cites W1585223519 @default.
• W2949304880 cites W1973421950 @default.
• W2949304880 cites W1977653864 @default.
• W2949304880 cites W1982590801 @default.
• W2949304880 cites W1986110505 @default.
• W2949304880 cites W2006532314 @default.
• W2949304880 cites W2011441884 @default.
• W2949304880 cites W2021464671 @default.
• W2949304880 cites W2022651708 @default.
• W2949304880 cites W2038172610 @default.
• W2949304880 cites W2085725184 @default.
• W2949304880 cites W2105115512 @default.
• W2949304880 cites W2113353077 @default.
• W2949304880 cites W2136586685 @default.
• W2949304880 cites W2147804311 @default.
• W2949304880 cites W2159986020 @default.
• W2949304880 cites W2949409323 @default.
• W2949304880 cites W2950451806 @default.
• W2949304880 cites W2952629859 @default.
• W2949304880 cites W2952667049 @default.
• W2949304880 cites W2953136108 @default.
• W2949304880 cites W2991673424 @default.
• W2949304880 doi "https://doi.org/10.1021/ic502955h" @default.
• W2949304880 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25731609" @default.
• W2949304880 hasPublicationYear "2015" @default.
• W2949304880 type Work @default.
• W2949304880 sameAs 2949304880 @default.
• W2949304880 citedByCount "8" @default.
• W2949304880 countsByYear W29493048802015 @default.
• W2949304880 countsByYear W29493048802017 @default.
• W2949304880 countsByYear W29493048802018 @default.
• W2949304880 countsByYear W29493048802019 @default.
• W2949304880 countsByYear W29493048802021 @default.
• W2949304880 countsByYear W29493048802022 @default.
• W2949304880 crossrefType "journal-article" @default.
• W2949304880 hasAuthorship W2949304880A5017376122 @default.
• W2949304880 hasAuthorship W2949304880A5047592331 @default.
• W2949304880 hasAuthorship W2949304880A5074696645 @default.
• W2949304880 hasConcept C105239961 @default.
• W2949304880 hasConcept C106773901 @default.
• W2949304880 hasConcept C115624301 @default.
• W2949304880 hasConcept C121332964 @default.
• W2949304880 hasConcept C161790260 @default.
• W2949304880 hasConcept C178790620 @default.
• W2949304880 hasConcept C185592680 @default.
• W2949304880 hasConcept C191897082 @default.
• W2949304880 hasConcept C192562407 @default.
• W2949304880 hasConcept C2777855556 @default.
• W2949304880 hasConcept C2781311116 @default.
• W2949304880 hasConcept C3018013958 @default.
• W2949304880 hasConcept C37407028 @default.
• W2949304880 hasConcept C544153396 @default.
• W2949304880 hasConcept C55493867 @default.
• W2949304880 hasConcept C61276311 @default.
• W2949304880 hasConcept C66882249 @default.
• W2949304880 hasConcept C8010536 @default.
• W2949304880 hasConcept C97355855 @default.
• W2949304880 hasConceptScore W2949304880C105239961 @default.
• W2949304880 hasConceptScore W2949304880C106773901 @default.
• W2949304880 hasConceptScore W2949304880C115624301 @default.
• W2949304880 hasConceptScore W2949304880C121332964 @default.
• W2949304880 hasConceptScore W2949304880C161790260 @default.
• W2949304880 hasConceptScore W2949304880C178790620 @default.
• W2949304880 hasConceptScore W2949304880C185592680 @default.
• W2949304880 hasConceptScore W2949304880C191897082 @default.
• W2949304880 hasConceptScore W2949304880C192562407 @default.
• W2949304880 hasConceptScore W2949304880C2777855556 @default.
• W2949304880 hasConceptScore W2949304880C2781311116 @default.
• W2949304880 hasConceptScore W2949304880C3018013958 @default.
• W2949304880 hasConceptScore W2949304880C37407028 @default.
• W2949304880 hasConceptScore W2949304880C544153396 @default.
• W2949304880 hasConceptScore W2949304880C55493867 @default.
• W2949304880 hasConceptScore W2949304880C61276311 @default.
• W2949304880 hasConceptScore W2949304880C66882249 @default.
• W2949304880 hasConceptScore W2949304880C8010536 @default.
• W2949304880 hasConceptScore W2949304880C97355855 @default.
• W2949304880 hasFunder F4320334593 @default.
• W2949304880 hasIssue "6" @default.
• W2949304880 hasLocation W29493048801 @default.
• W2949304880 hasLocation W29493048802 @default.
• W2949304880 hasOpenAccess W2949304880 @default.
• W2949304880 hasPrimaryLocation W29493048801 @default.
• W2949304880 hasRelatedWork W1965251697 @default.
• W2949304880 hasRelatedWork W2019849157 @default.
• W2949304880 hasRelatedWork W2024163631 @default.
• W2949304880 hasRelatedWork W2026477019 @default.
• W2949304880 hasRelatedWork W2047276591 @default.
• W2949304880 hasRelatedWork W2068256843 @default.
• W2949304880 hasRelatedWork W2330249236 @default.
• W2949304880 hasRelatedWork W2594900135 @default.

• next