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- W2949313500 abstract "Ruthenium complexes [Ru(L1)2(CH3CN)2](PF6)2 (1), [RuL1(CH3CN)4](PF6)2 (2) and [RuL2(CH3CN)3](PF6)2 (3) (L1= 3-methyl-1-(pyrimidine-2-yl)imidazolylidene, L2 = 1,3-bis(pyridin-2-ylmethyl)benzimidazolylidene) were obtained through a transmetallation reaction of the corresponding nickel-NHC complexes with [Ru(p-cymene)2Cl2]2 in refluxing acetonitrile solution. The crystal structures of three complexes determined by X-ray analyses show that the central Ru(II) atoms are coordinated by pyrimidine- or pyridine-functionalized N-heterocyclic carbene and acetonitrile ligands displaying the typical octahedral geometry. The reaction of [RuL1(CH3CN)4](PF6)2 with triphenylphosphine and 1,10-phenanthroline resulted in the substitution of one and two coordinated acetonitrile ligands and afforded [RuL1(PPh3)(CH3CN)3](PF6)2 (4) and [RuL1(phen)(CH3CN)2](PF6)2 (5), respectively. The molecular structures of the complexes 4 and 5 were also studied by X-ray diffraction analysis. These ruthenium complexes have proven to be efficient catalysts for transfer hydrogenation of various ketones." @default.
- W2949313500 created "2019-06-27" @default.
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- W2949313500 date "2015-11-12" @default.
- W2949313500 modified "2023-09-25" @default.
- W2949313500 title "ChemInform Abstract: Synthesis and Structures of Ruthenium-NHC Complexes and Their Catalysis in Hydrogen Transfer Reaction." @default.
- W2949313500 cites W2137763552 @default.
- W2949313500 doi "https://doi.org/10.1002/chin.201548044" @default.
- W2949313500 hasPublicationYear "2015" @default.
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