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- W2949314454 abstract "Cyclopentadienyl (Cp) complexes of main-group elements are classified and compared in terms of structural types, bonding features, and characteristic reactions. Halfsandwich, sandwich and multidecker sandwich arrangements of different type are observed Including cluster species with weak or strong metal-metal bonds. The Cp-E1 bonding ranges from mainly covalent to purely ionic with important structure-determining inter molecular contacts in the latter. pi-Complexation allows the stabilisation of compounds with low-valent elements such as Al(I), Ga(I), and Si(II). Important reaction principles and applications are shortly described." @default.
- W2949314454 created "2019-06-27" @default.
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- W2949314454 date "1999-01-01" @default.
- W2949314454 modified "2023-09-27" @default.
- W2949314454 title "Sandwich-type cyclopentadienyl complexes of main-group elements" @default.
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