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- W2949336716 abstract "The phosphine-mediated olefination of aldehydes with electron-deficient allenes to afford trisubstituted conjugated dienes in fair to excellent yields with high E-selectivity is described. The reaction represents a new reactivity pattern of allenes with aldehydes and also provides a highly stereoselective synthetic method for preparing conjugated dienes. In the reaction, the phosphine acts as a nucleophilic promoter to generate in situ an active phosphorus ylide which mediates the intermolecular olefination." @default.
- W2949336716 created "2019-06-27" @default.
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- W2949336716 date "2009-07-06" @default.
- W2949336716 modified "2023-09-23" @default.
- W2949336716 title "Phosphine-Mediated Olefination between Aldehydes and Allenes: An Efficient Synthesis of Trisubstituted 1,3-Dienes with High <i>E</i>-Selectivity" @default.
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- W2949336716 doi "https://doi.org/10.1021/ol901334c" @default.
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