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- W2949354003 abstract "Abstract We have investigated the influence of substituting P by As and As by Sb on the thermoelectric properties of LaFe 4 X 12 (X = P, As and Sb) compounds. It has been found that substituting P → As → Sb show significant influence on the bands dispersions, bond lengths, effective masses, the carriers mobility and hence the transport properties. Replacing P by As cause significant increases in the carriers concentration with increasing the temperatures, while replacing As by Sb exhibit insignificant increase in the carriers concentration of LaFe 4 Sb 12 with respect to LaFe 4 As 12 . It is clear that LaFe 4 As 12 show the highest electrical conductivity among the other compounds along the temperature range. Calculations show that LaFe 4 Sb 12 exhibit low electronic thermal conductivity in the temperature range between 50 and 600 K, then above 650 K the LaFe 4 P 12 compound show the lower electronic thermal conductivity. The Seebeck coefficient of LaFe 4 X 12 (X = P, As and Sb) compounds increases with increasing the temperature. Moving from P → As → Sb cause significant increases in the Seebeck coefficient and LaFe 4 Sb 12 compound exhibit the highest Seebeck coefficient along whole temperature scale. The power factor of LaFe 4 X 12 (X = P, As and Sb) compounds increases with increasing the temperature and LaFe 4 Sb 12 compound show the highest power factor along the whole temperature range." @default.
- W2949354003 created "2019-06-27" @default.
- W2949354003 creator A5073086267 @default.
- W2949354003 date "2015-11-19" @default.
- W2949354003 modified "2023-09-27" @default.
- W2949354003 title "ChemInform Abstract: Effect of X on the Transport Properties of Skutterudites LaFe4X12(X: P, As and Sb) Compounds." @default.
- W2949354003 cites W2463884175 @default.
- W2949354003 doi "https://doi.org/10.1002/chin.201549005" @default.
- W2949354003 hasPublicationYear "2015" @default.
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