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- W2949357910 abstract "The stereospecific synthesis of the monoterpene alkaloids (−)-α-skytanthine ((−)-2), (−)-N -demethyle-δ-sky-tanthine((−)-7), and (+)-epidihydrotecomanine (+)-4 was achieved from a common intermediate 22, which in turn was obtained from (1R,4S,1′S)-2-(1′-phenylethyl)-2-azabicyclo[2.2.1]hept-5-ene (10),via a ketene aza-Claisen rearrangement. The piperidine derivative (+)-31, formally the aza-analogue of (+)-isoiridomyrmecin, was also obtained from the same intermediate 22." @default.
- W2949357910 created "2019-06-27" @default.
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- W2949357910 date "1993-06-30" @default.
- W2949357910 modified "2023-10-16" @default.
- W2949357910 title "Enantioselective Synthesis of 3- Azabicyclo[4.3.0]nonane Alkaloids" @default.
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- W2949357910 doi "https://doi.org/10.1002/hlca.19930760416" @default.
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