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- W2949372474 abstract "2-Formylazulene and its derivatives were prepared by the oxidative cleavage of styrylazulenes with NaIO4−OsO4. 1,2-Diformyl-, 1,2,3-triformylazulenes, and 5-formylazulene derivative were also synthesized. The reaction of dimethyl 2-methylazulene-1,3-dicarboxylate with p-nitroso-N,N-dimethylaniline in the presence of NaOR (R=Me or Et) gave the corresponding 3-alkoxycarbonyl-2-[p-(dimethylamino)phenyliminomethyl]azulene-1-carboxylic acids followed by hydrolysis with hydrochloric acid to give 3-alkoxycarbonyl-2-formylazulene-1-carboxylic acids. Acetylation of 2-formylazulene-1-carboxylic acids with acetic anhydride gave five membered lactol acetates." @default.
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- W2949372474 date "1981-04-07" @default.
- W2949372474 modified "2023-09-25" @default.
- W2949372474 title "ChemInform Abstract: SYNTHESIS OF 2-FORMYLAZULENE AND ITS DERIVATIVES BY OXIDATIVE CLEAVAGE OF 2-STYRYLAZULENES" @default.
- W2949372474 cites W1986241041 @default.
- W2949372474 doi "https://doi.org/10.1002/chin.198114165" @default.
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