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- W2949372502 abstract "An efficient continuous flow iron-catalyzed Kumada cross-coupling was developed for the coupling of 2-chloropyrazine and various aryl Grignard reagents in presence of low catalyst loadings (0.5 mol-%). Compared to batch mode, the continuous flow approach overcomes the exothermicity which enabled longer catalyst lifetime, facilitated scale-up and significantly improved the yield. To the best of our knowledge, this is the first example of flow iron-catalyzed Kumada cross-coupling reactions which addresses scale dependence issues which often plague Kumada reactions carried out in the traditional batch mode." @default.
- W2949372502 created "2019-06-27" @default.
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- W2949372502 date "2016-09-01" @default.
- W2949372502 modified "2023-09-24" @default.
- W2949372502 title "ChemInform Abstract: Efficient Iron-Catalyzed Kumada Cross-Coupling Reactions Utilizing Flow Technology under Low Catalyst Loadings." @default.
- W2949372502 cites W2336465557 @default.
- W2949372502 doi "https://doi.org/10.1002/chin.201641190" @default.
- W2949372502 hasPublicationYear "2016" @default.
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