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- W2949380102 abstract "Abstract Bicyclo (2.2.2) octanes disposed with β,γ-unsaturated carbonyl chromophore are versatile intermediates for the synthesis of many carbocyclic structures of current interest1. Recently they have also been shown to have great potential towards synthesis of a variety of natural products2. We became interested in acquisition of functionalized annulated bicyclo (2.2.2) octenones of type 1 (Scheme-1) in connection with an exploratory project on the synthesis of polycyclopentanoids. In this context we recently reported that a trapping of a 2, 4-cyclohexadienone with cyclic dienes provides a facile entry into such ring systems3. We now further report an expeditious one step synthesis of annulated bicyclo (2.2.2) octenones 10–15 (Scheme-1) by trapping the 2, 4-cyclohexadienone 3 with various dienophiles 4–9(Scheme-1)." @default.
- W2949380102 created "2019-06-27" @default.
- W2949380102 creator A5001508065 @default.
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- W2949380102 date "1989-10-03" @default.
- W2949380102 modified "2023-09-23" @default.
- W2949380102 title "ChemInform Abstract: A Simple Synthesis of Annulated Bicyclo(2.2.2)octenones." @default.
- W2949380102 cites W2059909655 @default.
- W2949380102 doi "https://doi.org/10.1002/chin.198940176" @default.
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