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- W2949394476 abstract "A new inorganic supramolecular complex [Hg6As4](InCl6)Cl was synthesized. The complex crystallizes in the cubic space group Pa3 with the unit cell parameter a = 12.109(1) A and Z = 4. The crystal structure of the complex is based on the ∞3[Hg6As4]4+ three-dimensional cationic host framework. The guest InCl63– and Cl– anions are located in the cavities of the framework. The host—guest interactions were examined by quantum-chemical calculations of the equilibrium geometry of the InCl63– anion and analysis of the periodic zero-potential surface of the supramolecular complex. It was demonstrated that the electrostatic factors dominate over the covalent factors in the organization of the supramolecular structure of [Hg6As4](InCl6)Cl." @default.
- W2949394476 created "2019-06-27" @default.
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- W2949394476 date "2010-05-19" @default.
- W2949394476 modified "2023-09-24" @default.
- W2949394476 title "ChemInform Abstract: Synthesis and the Crystal Structure of [Hg6As4](InCl6)Cl: Influence of Covalent and Electrostatic Factors on the Supramolecular Structure." @default.
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- W2949394476 doi "https://doi.org/10.1002/chin.200238012" @default.
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