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- W2949409242 abstract "As important intermediates for blue emitting materials of organic light-emitting diodes, bromotriphenylethylene derivatives for distrylarylenes are prepared by reactions of bromobenzophenone with benzylphosphonates. The reaction produces a 60 : 40 mixture of (Z)- and (E)-geometric isomers that are difficult to be resolved. The (Z)-isomer is successfully isolated by a selective recrystallization process using 2-propanol as a solvent. The X-ray structure analysis of (Z)-isomer shows that dihedral angles between tert-butylphenyl ring and bromophenyl ring and between bromophenyl ring and phenyl ring are 56.5(4) and 74.1(4), respectively." @default.
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- W2949409242 date "2009-01-01" @default.
- W2949409242 modified "2023-09-24" @default.
- W2949409242 title "Synthesis and X-ray Structure Analysis of (Z)-1-(4-Bromophenyl)-1-phenyl -2-(4-tert-butylphenyl)ethene" @default.
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