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• W2949422148 abstract "Six new thioantimonates(III) with the [Sb4S7]2− anion were obtained under solvothermal conditions with in-situ formed transition metal complexes as structure directors. In the two isostructural compounds [Fe(dien)2]Sb4S7·H2O (1) and [Co(dien)2]Sb4S7·0.5 H2O (2) (dien = diethylenetriamine; space group: P21/c) the layered [Sb4S7]2− anion is characterized by Sb8S8 rings with a diameter of about 9.6·7.6Å. The cation complexes are located above and below the pores of the rings. Despite the larger size of the cation complex the network topology of the third thioantimonate [Ni(dien)(tren)]Sb4S7 (3) (tren = tris(2-aminoethyl)amine; space group: P21/n) is similar to that of the first two compounds. In the isostructural thioantimonates [M(trien)]Sb4S7 (M = Zn (4); M = Mn (5); trien = triethylenetetramine; space group: ) the M2+ ions are fivefold coordinated by four N atoms of the amine molecule and by one S atom of the thioantimonate anion forming a MN4S trigonal bipyramid. Sb8S16 building blocks are the central structural motifs of the anion. Two of the terminal S atoms at the periphery of the Sb8S16 units are bound to M2+ ions and the four remaining terminal S atoms connect adjacent Sb8S16 groups into the final [Sb4S7]2− chain. [Ni(tren)]Sb4S7 (6) (space group: ) contains a one-dimensional anionic chain. The Ni2+ ion has two bonds to the [Sb4S7]2− anion which is a unique feature in the thioantimonate(III) chemistry. The NiN4S2 octahedron is severly distorted with one very long Ni-S bond of 2.782(2) Å. In all compounds several short S···H distances indicate hydrogen bonding interactions." @default.
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• W2949422148 date "2008-08-01" @default.
• W2949422148 modified "2023-09-30" @default.
• W2949422148 title "On the Flexibility of Thioantimonate Networks: Solvothermal Syntheses and Crystal Structures of Six New Thioantimonates(III) with the [Sb₄S₇]²⁻Anion" @default.
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• W2949422148 doi "https://doi.org/10.1002/zaac.200800176" @default.
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