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• W2949443144 abstract "The gold-catalyzed Friedlander reaction was applied to the condensation of 2-aminoarylketones with β-keto-esters, β-diketones, β-keto-amides, and β-keto-sulfones to afford a diverse range of 2,3,4-trisubstituted quinolines in 3–82% yield. The seven-membered rings 1,3-cycloheptadione and azepane-2,4-dione reacted smoothly in 75% yield. An alternative procedure for the synthesis of 3-(methanesulfonyl)quinolines was developed and provided an entry into late stage manipulation of the 4-position of these quinolines. The requisite 2-aminoarylketones for the Friedlander reaction were prepared in one pot by modified Sugasawa reaction using gallium(III) chloride and boron(III) chloride in 12–54% yield." @default.
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• W2949443144 date "2007-03-01" @default.
• W2949443144 modified "2023-10-16" @default.
• W2949443144 title "New vistas in quinoline synthesis" @default.
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• W2949443144 doi "https://doi.org/10.1016/j.tet.2007.01.050" @default.
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