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- W2949445712 abstract "Abstract Intramolecular free-radical addition to propiolate esters has provided a new and a stereoselective route to 14–16 membered trans -α,β-unsaturated macrocylic lactones from their corresponding ω-iodoalkyl-propionate esters under triphenyltin hydride/AIBN mediated conditions. Attemps to synthesise analogous 10–13 membered lactones proved unsuccessful, resulting in acyclic products derived from direct reduction at the radical centre." @default.
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- W2949445712 date "1992-01-01" @default.
- W2949445712 modified "2023-09-27" @default.
- W2949445712 title "Free radical macrocyclisation via propiolate esters." @default.
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- W2949445712 doi "https://doi.org/10.1016/0040-4020(92)85015-7" @default.
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