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- W2949473035 abstract "The oxidative treatment of vinyltris(trimethylsilyl)germanes with hydrogen peroxide (NaOH/H2O/THF) or tert-butyl peroxide (KH/THF) generates reactive germanol or germanoxane species that undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides and aryl triflates in the presence of Pd(PPh3)4. Vinylgermanes having either a conjugated or isolated double bond serve as versatile transmetalation reagents. The E-germanes undergo coupling with retention of stereochemistry under aqueous and anhydrous conditions, while coupling of Z-germanes occurs with less stereoselectivity to produce a mixture of E/Z products." @default.
- W2949473035 created "2019-06-27" @default.
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- W2949473035 date "2005-03-12" @default.
- W2949473035 modified "2023-09-30" @default.
- W2949473035 title "Application of Vinyl Tris(trimethylsilyl)germanes in Pd-Catalyzed Couplings" @default.
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- W2949473035 doi "https://doi.org/10.1021/jo047773g" @default.
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