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- W2949474808 abstract "Abstract The quaternary chalcohalide Ba 4 Sb 3 S 8 Cl has been prepared from stoichiometric mixtures of BaCl 2 , Ba, Sb, and S at 1093 K in an evacuated silica tube. Ba 4 Sb 3 S 8 Cl crystallizes in the monoclinic P 2 1 /c space group and features a 0D structure containing totally isolated [SbS 3 ] 3− units and discrete SbS 2 Cl trigonal pyramids separated by Ba 2+ cations. The [SbS 3 ] 3− units and SbS 2 Cl trigonal pyramids are further packed in a pseudolayer motif in bc plane, respectively. The [SbS 3 ] 3− units are built by dimeric Sb 2 S 6 polyhedras and SbS 3 trigonal pyramids. Within the dimeric Sb 2 S 6 polyhedra, two SbS 4 seesaws share edges, while two SbS 3 trigonal pyramids share corners with dimeric Sb 2 S 6 polyhedra. The optical gap of 2.09 eV for Ba 4 Sb 3 S 8 Cl was deduced from the UV/Vis reflectance spectroscopy." @default.
- W2949474808 created "2019-06-27" @default.
- W2949474808 creator A5022469389 @default.
- W2949474808 date "2016-04-01" @default.
- W2949474808 modified "2023-09-26" @default.
- W2949474808 title "ChemInform Abstract: Synthesis, Crystal Structure, and Optical Property of the Quaternary Chalcohalide Ba4Sb3S8Cl." @default.
- W2949474808 cites W2189773436 @default.
- W2949474808 doi "https://doi.org/10.1002/chin.201617015" @default.
- W2949474808 hasPublicationYear "2016" @default.
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