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- W2949482310 abstract "We report a rhodium(II)-catalyzed highly enantioselective 1,3-dipolar cycloaddition reaction between the carbonyl moiety of tropone and carbonyl ylides to afford troponoids in good to high yields with excellent enantioselectivity. We demonstrate that α-diazoketone-derived carbonyl ylides, in contrast to carbonyl ylides derived from diazodiketoesters, undergo [6+3] cycloaddition reactions with tropone to yield the corresponding bridged heterocycles with excellent stereoselectivity." @default.
- W2949482310 created "2019-06-27" @default.
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- W2949482310 date "2015-10-01" @default.
- W2949482310 modified "2023-09-27" @default.
- W2949482310 title "ChemInform Abstract: Rhodium(II)-Catalyzed Enantioselective Synthesis of Troponoids." @default.
- W2949482310 cites W2115655227 @default.
- W2949482310 doi "https://doi.org/10.1002/chin.201543028" @default.
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