Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949491507> ?p ?o ?g. }
- W2949491507 endingPage "520" @default.
- W2949491507 startingPage "514" @default.
- W2949491507 abstract "A lanthanoid metal-mediated novel reductive dimerization/oxidative dehydrogenation of a variety of aldimines has been achieved. Aromatic aldimines (1) were dimerized in the presence of 0.5 mol of ytterbium metal (Yb) and 1-naphthaldehyde (1-NpCHO) to give the corresponding vicinal diimines (2) in good to high yields. Samarium metal (Sm) or samarium(II) diiodide (SmI2) gives unsatisfied yields under the same reaction conditions. As an oxidant, 1-NpCHO gives the best result. In addition, HMPA plays an important role as a cosolvent in this reaction. Reaction of various aldimines with Yb metal is disscussed in detail. Moreover, it has been found that the electron-donating substitutents on the benzene ring promote the reaction and that the electron-withdrawing substitutents retard the reaction. The reaction of deuterated N-benzylideneaniline with Yb metal confirmed that transformation of the hydride occurred from aldimines to the oxidant aldehyde. The mechanism of the reaction was discussed." @default.
- W2949491507 created "2019-06-27" @default.
- W2949491507 creator A5005452329 @default.
- W2949491507 creator A5028578213 @default.
- W2949491507 creator A5044979361 @default.
- W2949491507 creator A5089343696 @default.
- W2949491507 date "2000-12-28" @default.
- W2949491507 modified "2023-10-16" @default.
- W2949491507 title "A Novel Reductive Dimerization/Oxidative Dehydrogenation of Aldimines Mediated by Lanthanoid Metals" @default.
- W2949491507 cites W1554389304 @default.
- W2949491507 cites W1571291564 @default.
- W2949491507 cites W1966227525 @default.
- W2949491507 cites W1969836553 @default.
- W2949491507 cites W1969965914 @default.
- W2949491507 cites W1969987704 @default.
- W2949491507 cites W1974261154 @default.
- W2949491507 cites W1974445446 @default.
- W2949491507 cites W1977317445 @default.
- W2949491507 cites W1977692401 @default.
- W2949491507 cites W1981291217 @default.
- W2949491507 cites W1990852473 @default.
- W2949491507 cites W1992562263 @default.
- W2949491507 cites W1994944592 @default.
- W2949491507 cites W2006276017 @default.
- W2949491507 cites W2012667271 @default.
- W2949491507 cites W2013273973 @default.
- W2949491507 cites W2026847323 @default.
- W2949491507 cites W2027668772 @default.
- W2949491507 cites W2027678487 @default.
- W2949491507 cites W2030958085 @default.
- W2949491507 cites W2031839197 @default.
- W2949491507 cites W2032218899 @default.
- W2949491507 cites W2032924705 @default.
- W2949491507 cites W2041867385 @default.
- W2949491507 cites W2045783720 @default.
- W2949491507 cites W2045821990 @default.
- W2949491507 cites W2056581860 @default.
- W2949491507 cites W2058170511 @default.
- W2949491507 cites W2062763582 @default.
- W2949491507 cites W2062906630 @default.
- W2949491507 cites W2069186465 @default.
- W2949491507 cites W2069778813 @default.
- W2949491507 cites W2089343610 @default.
- W2949491507 cites W2091981592 @default.
- W2949491507 cites W2116989579 @default.
- W2949491507 cites W2128148021 @default.
- W2949491507 cites W2145661841 @default.
- W2949491507 cites W2146298124 @default.
- W2949491507 cites W2160489485 @default.
- W2949491507 cites W2314034944 @default.
- W2949491507 cites W2949528587 @default.
- W2949491507 cites W2951376058 @default.
- W2949491507 cites W2951858415 @default.
- W2949491507 cites W2951881716 @default.
- W2949491507 cites W2951981144 @default.
- W2949491507 cites W2952488900 @default.
- W2949491507 cites W2952639395 @default.
- W2949491507 cites W2953182475 @default.
- W2949491507 cites W2953202592 @default.
- W2949491507 cites W4211110382 @default.
- W2949491507 doi "https://doi.org/10.1021/jo001328d" @default.
- W2949491507 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11429823" @default.
- W2949491507 hasPublicationYear "2000" @default.
- W2949491507 type Work @default.
- W2949491507 sameAs 2949491507 @default.
- W2949491507 citedByCount "19" @default.
- W2949491507 countsByYear W29494915072012 @default.
- W2949491507 countsByYear W29494915072014 @default.
- W2949491507 countsByYear W29494915072015 @default.
- W2949491507 countsByYear W29494915072018 @default.
- W2949491507 countsByYear W29494915072019 @default.
- W2949491507 countsByYear W29494915072022 @default.
- W2949491507 countsByYear W29494915072023 @default.
- W2949491507 crossrefType "journal-article" @default.
- W2949491507 hasAuthorship W2949491507A5005452329 @default.
- W2949491507 hasAuthorship W2949491507A5028578213 @default.
- W2949491507 hasAuthorship W2949491507A5044979361 @default.
- W2949491507 hasAuthorship W2949491507A5089343696 @default.
- W2949491507 hasConcept C119889771 @default.
- W2949491507 hasConcept C155647269 @default.
- W2949491507 hasConcept C161790260 @default.
- W2949491507 hasConcept C178790620 @default.
- W2949491507 hasConcept C185592680 @default.
- W2949491507 hasConcept C2776573223 @default.
- W2949491507 hasConcept C536819264 @default.
- W2949491507 hasConcept C544153396 @default.
- W2949491507 hasConcept C67524406 @default.
- W2949491507 hasConcept C75473681 @default.
- W2949491507 hasConceptScore W2949491507C119889771 @default.
- W2949491507 hasConceptScore W2949491507C155647269 @default.
- W2949491507 hasConceptScore W2949491507C161790260 @default.
- W2949491507 hasConceptScore W2949491507C178790620 @default.
- W2949491507 hasConceptScore W2949491507C185592680 @default.
- W2949491507 hasConceptScore W2949491507C2776573223 @default.
- W2949491507 hasConceptScore W2949491507C536819264 @default.
- W2949491507 hasConceptScore W2949491507C544153396 @default.
- W2949491507 hasConceptScore W2949491507C67524406 @default.
- W2949491507 hasConceptScore W2949491507C75473681 @default.