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- W2949496619 abstract "Abstract Treatment of mixed anhydrides derived from cis‐ and trans ‐2‐carbobenzyloxycyclopropanecarboxylic acids and ethyl chloroformate with ethoxymagnesio di‐ tert ‐butyl malonate and subsequent treatment of the resulting adducts with p ‐toluenesulfonic acid afforded cis‐ and trans‐ benzyl 2‐acetylcyclopropanecar‐boxylates in good to excellent yields, with retention of the original stereochemistry of the systems. These methyl ketones and an open chain congener, benzyl levulinate, were inert toward m‐ chloroper‐benzoic acid. The cis‐ isomer and benzyl levulinate underwent normal Baeyer‐Villiger reactions mediated by trifluoroperacetic acid, forming moderate yields of the acetate ester insertion products." @default.
- W2949496619 created "2019-06-27" @default.
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- W2949496619 creator A5032060139 @default.
- W2949496619 date "1975-10-07" @default.
- W2949496619 modified "2023-09-27" @default.
- W2949496619 title "ChemInform Abstract: PREPARATION AND BAEYER-VILLIGER REACTION OF CERTAIN 2-CARBALKOXYCYCLOPROPYL METHYL KETONES" @default.
- W2949496619 cites W1971301689 @default.
- W2949496619 doi "https://doi.org/10.1002/chin.197540145" @default.
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