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- W2949531188 abstract "The present paper presents a mechanism for the reaction between trivalent phosphorus compounds - P(OR)3, R = alkyl and P {N(CH3)2}3 - and molecules with activated carbonyl groups such as α-diketones, o-quinones and α,β-unsaturated ketones. It appeared from ESR measurements that intermediate radicals which originate in a high concentration are converted into oxyphosphoranes. In the case of P(OR)3 an intramolecular shift could be established as a side reaction. Furthermore a number of interesting spin adducts are formed between phosphinium radicals and the scavenger 2-methyl-2-nitrosopropane." @default.
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- W2949531188 date "1974-10-22" @default.
- W2949531188 modified "2023-09-26" @default.
- W2949531188 title "ChemInform Abstract: ELECTRON TRANSFER REACTIONS BETWEEN TRIVALENT PHOSPHORUS COMPOUNDS AND ACTIVATED KETONES" @default.
- W2949531188 cites W1989115625 @default.
- W2949531188 doi "https://doi.org/10.1002/chin.197442362" @default.
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