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- W2949533845 abstract "Iridium-catalyzed, asymmetric allylation of ammonia as a nucleophile occurs with stereoselectivity to form a symmetric diallylamine, and related allylation of the inexpensive ammonia equivalent potassium trifluoroacetamide or the highly reactive ammonia equivalent lithium di-tert-butyliminodicarboxylate forms a range of conveniently protected, primary, alpha-branched allylic amines in high yields, high branched-to-linear regioselectivities, and high enantiomeric excess. The reactions of ammonia equivalents were conducted with a catalyst generated from a phosphoramidite containing a single stereochemical element." @default.
- W2949533845 created "2019-06-27" @default.
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- W2949533845 date "2007-08-29" @default.
- W2949533845 modified "2023-10-16" @default.
- W2949533845 title "Enantioselective Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates" @default.
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- W2949533845 doi "https://doi.org/10.1021/ol701562p" @default.
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