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• W2949537295 abstract "Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] annulation reactions was investigated. The best results were obtained with diazomethane and substituted diazomethane reagents, which provided cyclopentenone products in excellent yields and essentially complete stereoselectivity." @default.
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• W2949537295 date "2006-07-26" @default.
• W2949537295 modified "2023-10-16" @default.
• W2949537295 title "Stereoselective [4 + 1] Annulation Reactions with Silyl Vinylketenes Derived from Fischer Carbene Complexes" @default.
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• W2949537295 doi "https://doi.org/10.1021/jo060994x" @default.
• W2949537295 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16901142" @default.
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