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• W2949541489 abstract "The title compound features a five-membered Ru5 ring embedded in a La14 hexagonal wheel-like cage, an incommensurate combination of the two building units. A formal electron partition of (La3+)14(Cl–)20(Ru5)22– results in a (Ru5)22– ring isoelectronic to (Cd5)2–. However, computational studies show that there is significant electron back-donation from the Ru5 ring to the La14 wheel. This interaction strongly stabilizes the Ru5 ring. The resistivity and magnetic susceptibility of the compound have also been investigated." @default.
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• W2949541489 date "2012-03-07" @default.
• W2949541489 modified "2023-10-03" @default.
• W2949541489 title "A Five-Membered Ru₅ Ring in a Hexagonal La₁₄ Cage: The La₁₄Cl₂₀Ru₅ Structure" @default.
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• W2949541489 doi "https://doi.org/10.1021/ja210846d" @default.
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