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- W2949550010 abstract "The methylperoxy radical has been isolated in matrices of Ar + 10% O2 and its IR spectrum observed. The following isotopic species were used in the investigation: CH3, 13CH3, CD3, 16O2, 18O2, and 16O18O. A total of 64 frequencies were identified for the various isotopically labelled peroxy radicals. A normal coordinate analysis for the methylperoxy radical has been made. Good agreement between the observed and calculated frequencies was obtained.Alkylperoxy- und Alkyl-Radikale. 2. Ultrarot-Spektrum und Normalkoordinaten-Analyse von CH3O2 und einigen isotopen MolekulenDas Methylperoxy-Radikal wurde in einer Matrix (Ar + 10% O2) isoliert und das IR-Spektrum aufgenommen. Die folgenden isotopen Molekule wurden eingesetzt und untersucht: CH3, 13CH3, CD3, 16O2, 18O2 und 16O18O. Im Gesamten wurden 64 Frequenzen den verschiedenen isotopen Peroxy-Radikalen zugeordnet. Es wurde eine Normalkoordinaten-Analyse des Methylperoxy-Radikals durchgefuhrt, die eine gute Ubereinstimmung zwischen beobachteten und berechneten Frequenzen ergab." @default.
- W2949550010 created "2019-06-27" @default.
- W2949550010 creator A5023581969 @default.
- W2949550010 creator A5048302623 @default.
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- W2949550010 date "1987-04-21" @default.
- W2949550010 modified "2023-10-13" @default.
- W2949550010 title "ChemInform Abstract: Alkylperoxy and Alkyl Radicals. Part 2. IR Spectra and Normal Coordinate Analysis of CH3O2 and Several Isotopically Labelled Species." @default.
- W2949550010 cites W1992918465 @default.
- W2949550010 doi "https://doi.org/10.1002/chin.198716048" @default.
- W2949550010 hasPublicationYear "1987" @default.
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