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- W2949554047 abstract "Asymmetric biocatalytic hydrolysis of (±)-2,3-disubstituted oxiranes leading to the formation of vicinal diols in up to 97% ee at 100% conversion was accomplished by using the epoxide hydrolase activity of various bacterial strains. The mechanism of this deracemization was elucidated by 18OH2-labelling experiments using a partially purified epoxide hydrolase from Nocardia EH1. The reaction was shown to proceed in an enantioconvergent fashion by attack of OH– at the (S)-configured oxirane carbon atom with concomitant inversion of configuration. A mathematical model developed for the description of the kinetics was verified by the determination of the four relative rate constants governing the regio- and enantio-selectivity of the process." @default.
- W2949554047 created "2019-06-27" @default.
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- W2949554047 date "2010-06-23" @default.
- W2949554047 modified "2023-09-25" @default.
- W2949554047 title "ChemInform Abstract: Deracemization of (.+-.)-2,3-Disubstituted Oxiranes via Biocatalytic Hydrolysis Using Bacterial Epoxide Hydrolases: Kinetics of an Enantioconvergent Process." @default.
- W2949554047 cites W2003489168 @default.
- W2949554047 doi "https://doi.org/10.1002/chin.199818122" @default.
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