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- W2949556978 abstract "Arene and heteroarenediazonium o-benzenedisulfonimides can be used as efficient reagents in Sandmeyer cyanation. This work reports such reactions carried out by us under very mild conditions using tetrabutyl ammonium cyanide as a safe cyanide source and, interestingly, without the need for a Cu catalyst. The reactions have given rise to aryl nitriles in good yields (25 examples, average yield 75%). A good amount of o-benzenedisulfonimide was recovered from each reaction and then reused to prepare other salts. Mechanistic insights have allowed us to highlight the fundamental role of the o-benzenedisulfonimide anion as an electron transfer agent." @default.
- W2949556978 created "2019-06-27" @default.
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- W2949556978 date "2016-05-01" @default.
- W2949556978 modified "2023-09-27" @default.
- W2949556978 title "ChemInform Abstract: Copper-Free Sandmeyer Cyanation of Arenediazonium o-Benzenedisulfonimides." @default.
- W2949556978 cites W2194961326 @default.
- W2949556978 doi "https://doi.org/10.1002/chin.201622084" @default.
- W2949556978 hasPublicationYear "2016" @default.
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