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- W2949565527 abstract "Abstract A fast new entry for the stereoselective construction of γ‐substituted vinyl sulfones is presented. The key for success is the use of a readily available chiral secondary amine catalyst that allows the use of base‐sensitive β‐nitroethyl sulfones as masked β‐sulfonyl vinyl anions in conjugate additions. The method performed in a three‐step one‐pot operation gives access to a great variety of vinyl sulfones in good yields and with excellent enantioselectivities. The method has also been extended to other relatively base‐sensitive β‐electron‐withdrawing‐substituted nitroalkanes to afford products with manifold functionality, providing a quick entry to very attractive synthetic intermediates for organic synthesis." @default.
- W2949565527 created "2019-06-27" @default.
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- W2949565527 date "2011-01-19" @default.
- W2949565527 modified "2023-10-18" @default.
- W2949565527 title "Catalytic Asymmetric Synthesis of γ-Substituted Vinyl Sulfones" @default.
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- W2949565527 doi "https://doi.org/10.1002/chem.201003177" @default.
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