Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949571502> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2949571502 abstract "The reactions of methyl radicals, generated by the photolysis of acetone, with cyclohexane and a number of methyl-substituted cyclohexanes have been studied. The Arrhenius parameters corresponding to overall hydrogen abstraction have been obtained from experiments in the temperature range 100–200 °C based on the value of the rate constant for recombination of methyl radicals. The overall rate constants for hydrogen abstraction by methyl radicals could be adequately expressed as the sum of contributions from each tertiary, secondary and primary hydrogen atom for all of the following nine compounds which were studied: cyclohexane, methylcy clohexane, 1,2-dimethylcyclohexane, 1,3-dimethylcyclohexane, 1,4-dimethylcyclohexane, 1,1-dimethylcyclohexane, 1,3,5-trimethylcyclohexane, 1,2,4-trimethylcyclohexane and 1,1,3-trimethylcyclohexane. The Arrhenius parameters for the abstraction of secondary hydrogen atoms are log (A/cm3 mol–1s–1)= 10.83, E/kJ mol–1= 37.4, and those for the abstraction of tertiary hydrogen atoms are log (A/cm3 mol–1 s–1)= 11.78, E/kJ mol–1= 35.7." @default.
- W2949571502 created "2019-06-27" @default.
- W2949571502 creator A5011114648 @default.
- W2949571502 creator A5078226591 @default.
- W2949571502 creator A5082863640 @default.
- W2949571502 date "1990-01-16" @default.
- W2949571502 modified "2023-09-27" @default.
- W2949571502 title "ChemInform Abstract: Reactions of Methyl Radicals with Cyclohexane and Methyl-Substituted Cyclohexanes" @default.
- W2949571502 cites W2061495073 @default.
- W2949571502 doi "https://doi.org/10.1002/chin.199003100" @default.
- W2949571502 hasPublicationYear "1990" @default.
- W2949571502 type Work @default.
- W2949571502 sameAs 2949571502 @default.
- W2949571502 citedByCount "0" @default.
- W2949571502 crossrefType "journal-article" @default.
- W2949571502 hasAuthorship W2949571502A5011114648 @default.
- W2949571502 hasAuthorship W2949571502A5078226591 @default.
- W2949571502 hasAuthorship W2949571502A5082863640 @default.
- W2949571502 hasConcept C121332964 @default.
- W2949571502 hasConcept C139066938 @default.
- W2949571502 hasConcept C147789679 @default.
- W2949571502 hasConcept C148898269 @default.
- W2949571502 hasConcept C155647269 @default.
- W2949571502 hasConcept C178790620 @default.
- W2949571502 hasConcept C185592680 @default.
- W2949571502 hasConcept C2776640939 @default.
- W2949571502 hasConcept C2778237882 @default.
- W2949571502 hasConcept C2780263894 @default.
- W2949571502 hasConcept C2781213060 @default.
- W2949571502 hasConcept C2910947881 @default.
- W2949571502 hasConcept C512968161 @default.
- W2949571502 hasConcept C62520636 @default.
- W2949571502 hasConcept C75473681 @default.
- W2949571502 hasConcept C81022585 @default.
- W2949571502 hasConcept C86183883 @default.
- W2949571502 hasConcept C93391505 @default.
- W2949571502 hasConcept C95121573 @default.
- W2949571502 hasConceptScore W2949571502C121332964 @default.
- W2949571502 hasConceptScore W2949571502C139066938 @default.
- W2949571502 hasConceptScore W2949571502C147789679 @default.
- W2949571502 hasConceptScore W2949571502C148898269 @default.
- W2949571502 hasConceptScore W2949571502C155647269 @default.
- W2949571502 hasConceptScore W2949571502C178790620 @default.
- W2949571502 hasConceptScore W2949571502C185592680 @default.
- W2949571502 hasConceptScore W2949571502C2776640939 @default.
- W2949571502 hasConceptScore W2949571502C2778237882 @default.
- W2949571502 hasConceptScore W2949571502C2780263894 @default.
- W2949571502 hasConceptScore W2949571502C2781213060 @default.
- W2949571502 hasConceptScore W2949571502C2910947881 @default.
- W2949571502 hasConceptScore W2949571502C512968161 @default.
- W2949571502 hasConceptScore W2949571502C62520636 @default.
- W2949571502 hasConceptScore W2949571502C75473681 @default.
- W2949571502 hasConceptScore W2949571502C81022585 @default.
- W2949571502 hasConceptScore W2949571502C86183883 @default.
- W2949571502 hasConceptScore W2949571502C93391505 @default.
- W2949571502 hasConceptScore W2949571502C95121573 @default.
- W2949571502 hasLocation W29495715021 @default.
- W2949571502 hasOpenAccess W2949571502 @default.
- W2949571502 hasPrimaryLocation W29495715021 @default.
- W2949571502 hasRelatedWork W1967522180 @default.
- W2949571502 hasRelatedWork W1983998568 @default.
- W2949571502 hasRelatedWork W1990040397 @default.
- W2949571502 hasRelatedWork W1996627949 @default.
- W2949571502 hasRelatedWork W1998978600 @default.
- W2949571502 hasRelatedWork W2036302689 @default.
- W2949571502 hasRelatedWork W2036459922 @default.
- W2949571502 hasRelatedWork W2044947064 @default.
- W2949571502 hasRelatedWork W2061495073 @default.
- W2949571502 hasRelatedWork W2073306999 @default.
- W2949571502 hasRelatedWork W2076206383 @default.
- W2949571502 hasRelatedWork W2082903935 @default.
- W2949571502 hasRelatedWork W2084087798 @default.
- W2949571502 hasRelatedWork W2086218604 @default.
- W2949571502 hasRelatedWork W2135176471 @default.
- W2949571502 hasRelatedWork W2144296613 @default.
- W2949571502 hasRelatedWork W2170129811 @default.
- W2949571502 hasRelatedWork W2330102697 @default.
- W2949571502 hasRelatedWork W2950614732 @default.
- W2949571502 hasRelatedWork W2951202602 @default.
- W2949571502 isParatext "false" @default.
- W2949571502 isRetracted "false" @default.
- W2949571502 magId "2949571502" @default.
- W2949571502 workType "article" @default.