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- W2949579658 abstract "Abstract Substituted hydronaphthalenes where each of the ten carbons of the two-ring system contains a functionality were obtained through a tandem [8+2] cycloaddition and base-catalyzed rearrangement process using dienylfurans and electron-deficient alkynes. If the [8+2] process is conducted under solvent-free conditions the process could be conducted in a single reaction flask without isolation of the chromatographically sensitive [8+2] cycloadducts. A mechanism involving base catalyzed alkene positional isomerization followed by disrotatory electrocyclic ring closure was proposed for the key reaction step that converts [8+2] cycloadducts to hydronaphthalenes. The products undergo selective ring opening–isomerization processes upon treatment with Lewis acids." @default.
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- W2949579658 date "2016-10-01" @default.
- W2949579658 modified "2023-09-23" @default.
- W2949579658 title "ChemInform Abstract: A Novel Stereoselective [8 + 2] Double Cycloaddition Route to Hydronaphthalene Ring Systems." @default.
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- W2949579658 doi "https://doi.org/10.1002/chin.201644025" @default.
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