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- W2949583639 abstract "In this study, samples of activated mesoporous carbon are fabricated with pore structures with cylinder and gyroid nanostructures through the templating effect of amphiphilic poly(ethylene oxide-block-caprolactone) (PEO-PCL) and by using specific resol/PEO-PCL weight ratios (e.g., 60:40 for cylinders; 55:45 for gyroids). After carbonization and KOH activation, the activated mesoporous carbons were tested as electrode materials for electric double-layer capacitor (EDLC) supercapacitors. The electrochemical properties were examined by using three-electrode (6 m KOH(aq) as electrolyte) and CR2032 coin-cell (1 m tetraethylammonium tetrafluoroborate (TEABF4 )/CN as the electrolyte) systems. The gyroid carbon samples provided specific capacitances higher than those of the cylinder carbon samples in both aqueous and organic systems: 155 F g-1 compared with 135 F g-1 in 6 m KOH(aq) , and 105.6 compared with 96 F g-1 in 1 m TEABF4 /MeCN, after 100 charge/discharge cycles. It is suspected that the bi-continuous mesochannels of the gyroid-type activated mesoporous carbons provided a relatively higher effective adsorption surface area; in other words, the greater surface area for energy storage originated from a moderate pore size and an interconnected pore structure." @default.
- W2949583639 created "2019-06-27" @default.
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- W2949583639 date "2019-07-08" @default.
- W2949583639 modified "2023-10-01" @default.
- W2949583639 title "Mesoporous Carbons Templated by PEO‐PCL Block Copolymers as Electrode Materials for Supercapacitors" @default.
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- W2949583639 doi "https://doi.org/10.1002/chem.201901724" @default.
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