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• W2949603764 startingPage "299" @default.
• W2949603764 abstract "Reduction and oxidation of perovskite-structure transition-metal oxide thin films are highlighted. Oxygen ions are released from and incorporated into the perovskite-structure framework during the reduction and oxidation. Low-temperature topochemical reduction reaction with CaH2 enables us to prepare infinite-layer structure oxide thin films containing Fe and Ni. With the epitaxially grown thin film samples, anisotropic rearrangement and transfer of oxygen ions in the structures have been revealed. Selective reduction of layers in artificial superlattices was also found, and the observed behavior suggests that the oxygen-ion mobility in the artificial superlattices was confined within the two-dimensional brownmillerite layer. Specific structural features play important roles in the oxygen-ion transfer in solids at low temperatures. The obtained results would be a key to develop technologies related to energy and the environment." @default.
• W2949603764 created "2019-06-27" @default.
• W2949603764 creator A5066804384 @default.
• W2949603764 date "2013-03-15" @default.
• W2949603764 modified "2023-10-01" @default.
• W2949603764 title "Reduction and Oxidation of Transition-Metal Oxide Thin Films: Solid-State Chemistry with Epitaxially Grown Thin Films" @default.
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• W2949603764 doi "https://doi.org/10.1246/bcsj.20120277" @default.
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