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- W2949617877 abstract "The structure of Rb2PO3F was determined at 290 and 130 K, while that of Cs2PO3F was determined at 240 and 100 K. Both compounds belong to the β-K2SO4 family. The structure analysis did not reveal signs of a phase transition in either compound. Crystal chemical considerations do not favour the presence of a phase transition in either Rb2PO3F or Cs2PO3F. However, glass-like phase transitions were observed by differential scanning calorimetry in slightly humid samples at 175 and 177 K for Rb2PO3F and Cs2PO3F, respectively, but were not observed in well dried samples. The bond distances are normal and Cs2PO3F is twinned." @default.
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- W2949617877 date "2006-05-24" @default.
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- W2949617877 title "Dirubidium fluorotrioxophosphate, Rb<sub>2</sub>PO<sub>3</sub>F, at 290 and 130 K, and dicaesium fluorotrioxophosphate, Cs<sub>2</sub>PO<sub>3</sub>F, at 240 and 100 K" @default.
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- W2949617877 doi "https://doi.org/10.1107/s0108270106016350" @default.
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