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- W2949618558 abstract "The antioxidant action of thiophenes is shown to be due to a heterolytic decomposition of hydroperoxides effected by SO2 (H2SO4) which is liberated from the thiophene. Thus, the initiation level in an autoxidizing alkylaromatic compound (n-hexylbenzene) is decreased and the oxidation is further inhibited by phenol, the heterolysis product of the hydroperoxide. At low thiophene concentrations the inhibition is counterbalanced by the low initiation level in such a way that the oxidation continues to proceed at a constant rate. The effect of substituents, of the concentration and of added bases on the antioxidant activity of thiophenes is reported." @default.
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- W2949618558 date "1976-09-14" @default.
- W2949618558 modified "2023-09-27" @default.
- W2949618558 title "ChemInform Abstract: MECHANISM OF THE INHIBITION OF AUTOXIDATION BY THIOPHENES" @default.
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- W2949618558 doi "https://doi.org/10.1002/chin.197637120" @default.
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