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- W2949632007 abstract "Cross-conjugated dienones bearing α-hydroxyalkyl substituents readily undergo Nazarov cyclization followed by deprotonation of the resulting cyclopentenyl cation, and β-elimination of the exocyclic hydroxy group to form alkylidenecyclopentenones in moderate yield. The deprotonation step occurs with complete regioselectivity opposite to the hydroxyalkyl substituent, with preferential introduction of an endocyclic olefin. The transformation is tolerant of a variety of substituents and occurs under relatively mild conditions." @default.
- W2949632007 created "2019-06-27" @default.
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- W2949632007 date "2015-01-15" @default.
- W2949632007 modified "2023-09-27" @default.
- W2949632007 title "ChemInform Abstract: Ready Access to Alkylidenecyclopentenones by Nazarov Cyclization/β-Elimination of 2-Hydroxyalkyl-1,4-dien-3-ones." @default.
- W2949632007 cites W1904043572 @default.
- W2949632007 doi "https://doi.org/10.1002/chin.201505077" @default.
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