Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949642163> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2949642163 endingPage "981" @default.
- W2949642163 startingPage "973" @default.
- W2949642163 abstract "A new and efficient synthesis of a variety of highly embellished bicyclooctenones having an endo-vinyl moiety and their sigmatropic shifts in ground and excited states leading to a stereoselective route to substituted cis-decalins and diquinane frameworks have been described. Functionalized bicyclo[2.2.2]octenones having an endo-vinyl group and a beta,gamma-enone chromophore were prepared by in situ generation of 6-chloromethyl-6-hydroxycyclohexadienones and cycloaddition with butadiene (also generated in situ) followed by manipulation of the adducts. The presence of contiguous carbonyl, hydroxyl, and chloromethyl groups in adducts led to the introduction of various alkyl groups alpha to the ketone in a stereoselective fashion. The 3,3-sigmatropic shift in the bridged bicyclic compounds gave the corresponding cis-decalins, whereas the triplet sensitized irradiation led to the formation of diquinanes as a result of a 1,2-acyl shift." @default.
- W2949642163 created "2019-06-27" @default.
- W2949642163 creator A5001508065 @default.
- W2949642163 creator A5014287826 @default.
- W2949642163 creator A5067285977 @default.
- W2949642163 date "2004-12-30" @default.
- W2949642163 modified "2023-10-09" @default.
- W2949642163 title "A Novel and Efficient Synthesis of Bicyclo[2.2.2]octenones and Sigmatropic Shifts in Ground and Excited States: Stereoselective Route to cis-Decalins and Diquinane Frameworks" @default.
- W2949642163 cites W1969614327 @default.
- W2949642163 cites W1971816032 @default.
- W2949642163 cites W1992648874 @default.
- W2949642163 cites W2001678880 @default.
- W2949642163 cites W2007038095 @default.
- W2949642163 cites W2012541899 @default.
- W2949642163 cites W2013351320 @default.
- W2949642163 cites W2019497815 @default.
- W2949642163 cites W2019519438 @default.
- W2949642163 cites W2030838584 @default.
- W2949642163 cites W2037767803 @default.
- W2949642163 cites W2042423353 @default.
- W2949642163 cites W2059909655 @default.
- W2949642163 cites W2082970072 @default.
- W2949642163 cites W2087921332 @default.
- W2949642163 cites W2319538524 @default.
- W2949642163 cites W2950122378 @default.
- W2949642163 cites W2951110086 @default.
- W2949642163 cites W2951964949 @default.
- W2949642163 cites W2952520695 @default.
- W2949642163 cites W2953228325 @default.
- W2949642163 cites W3004424765 @default.
- W2949642163 doi "https://doi.org/10.1021/jo048320e" @default.
- W2949642163 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15675857" @default.
- W2949642163 hasPublicationYear "2004" @default.
- W2949642163 type Work @default.
- W2949642163 sameAs 2949642163 @default.
- W2949642163 citedByCount "8" @default.
- W2949642163 countsByYear W29496421632014 @default.
- W2949642163 countsByYear W29496421632018 @default.
- W2949642163 countsByYear W29496421632022 @default.
- W2949642163 crossrefType "journal-article" @default.
- W2949642163 hasAuthorship W2949642163A5001508065 @default.
- W2949642163 hasAuthorship W2949642163A5014287826 @default.
- W2949642163 hasAuthorship W2949642163A5067285977 @default.
- W2949642163 hasConcept C108204754 @default.
- W2949642163 hasConcept C155647269 @default.
- W2949642163 hasConcept C161790260 @default.
- W2949642163 hasConcept C178790620 @default.
- W2949642163 hasConcept C181647583 @default.
- W2949642163 hasConcept C185592680 @default.
- W2949642163 hasConcept C24961977 @default.
- W2949642163 hasConcept C2776568683 @default.
- W2949642163 hasConcept C2776753869 @default.
- W2949642163 hasConcept C2777738585 @default.
- W2949642163 hasConcept C2779664164 @default.
- W2949642163 hasConcept C2779746879 @default.
- W2949642163 hasConcept C2780263894 @default.
- W2949642163 hasConcept C58590140 @default.
- W2949642163 hasConcept C71240020 @default.
- W2949642163 hasConceptScore W2949642163C108204754 @default.
- W2949642163 hasConceptScore W2949642163C155647269 @default.
- W2949642163 hasConceptScore W2949642163C161790260 @default.
- W2949642163 hasConceptScore W2949642163C178790620 @default.
- W2949642163 hasConceptScore W2949642163C181647583 @default.
- W2949642163 hasConceptScore W2949642163C185592680 @default.
- W2949642163 hasConceptScore W2949642163C24961977 @default.
- W2949642163 hasConceptScore W2949642163C2776568683 @default.
- W2949642163 hasConceptScore W2949642163C2776753869 @default.
- W2949642163 hasConceptScore W2949642163C2777738585 @default.
- W2949642163 hasConceptScore W2949642163C2779664164 @default.
- W2949642163 hasConceptScore W2949642163C2779746879 @default.
- W2949642163 hasConceptScore W2949642163C2780263894 @default.
- W2949642163 hasConceptScore W2949642163C58590140 @default.
- W2949642163 hasConceptScore W2949642163C71240020 @default.
- W2949642163 hasIssue "3" @default.
- W2949642163 hasLocation W29496421631 @default.
- W2949642163 hasLocation W29496421632 @default.
- W2949642163 hasOpenAccess W2949642163 @default.
- W2949642163 hasPrimaryLocation W29496421631 @default.
- W2949642163 hasRelatedWork W1984948204 @default.
- W2949642163 hasRelatedWork W1998570974 @default.
- W2949642163 hasRelatedWork W2022460769 @default.
- W2949642163 hasRelatedWork W2063437815 @default.
- W2949642163 hasRelatedWork W2065506164 @default.
- W2949642163 hasRelatedWork W2077559426 @default.
- W2949642163 hasRelatedWork W2119807050 @default.
- W2949642163 hasRelatedWork W2951127070 @default.
- W2949642163 hasRelatedWork W2952284015 @default.
- W2949642163 hasRelatedWork W2952392961 @default.
- W2949642163 hasVolume "70" @default.
- W2949642163 isParatext "false" @default.
- W2949642163 isRetracted "false" @default.
- W2949642163 magId "2949642163" @default.
- W2949642163 workType "article" @default.