FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949642610> ?p ?o ?g. }

• W2949642610 endingPage "351" @default.
• W2949642610 startingPage "331" @default.
• W2949642610 abstract "This review is devoted to recent advances in mononuclear iron carbonyl coordination chemistry starting from M+[EFe(CO)4]− complexes (E=H, RCO) easily obtained from Fe(CO)5. E=H. The reaction of K+[HFe(CO)4]− with phosphines, phosphites and phosphinites (abbreviated “P”) allows selective syntheses for a large range of (phosphane)iron carbonyl complexes such as Fe(CO)3P2, Fe(CO)2P3, H2Fe(CO)2P2, K+[HFe(CO)3P]− and K+[HFe(CO)2P2]−. In the special case of the new optically active phosphinite–ammonium ligands P–(*)–N+ named “ephosium” and “valphosium”, optically active zwitterionic complexes [HFe(CO)3P]−–(*)–N+ have been obtained, the structures of which have been studied both in the solid state and in solution. The above reactions have been shown to involve first a CO substitution, generating [HFe(CO)3P]− species which then react further, the final product depending on both the nature of the solvent (protic or not) and the steric and electronic properties of the phosphane. In contrast, reaction with tri(amino)phosphines proceeds by substitution at the phosphorus atom, affording the Collman dianion [Fe(CO)4]2− and [(R2N)2PH]Fe(CO)4 complexes the reactivities of which with KH have been studied. E=RCO. The reaction of lithium aldimines such as [t-BuNC(t-Bu)]Li with Fe(CO)5 generates lithium (α-iminoacyl)tetracarbonylferrates, which are imino-protected equivalents of the rare [(CO)4Fe–CO–CO–Z]− sequence. Alkylation with Me3OBF4 yields the corresponding α,β-unsaturated Fischer carbene complexes. The reaction of RCO(Li)Fe(CO)4 (R=alkyl) with PPh2Cl (or PPhCl2) cleanly proceeds by a tandem acylation–complexation to afford the complexed acylphosphines [RCOPPh2]Fe(CO)4 (or [RCOPPhCl]Fe(CO)4) in good yield." @default.
• W2949642610 created "2019-06-27" @default.
• W2949642610 creator A5007130170 @default.
• W2949642610 creator A5032595692 @default.
• W2949642610 creator A5033317919 @default.
• W2949642610 creator A5048169052 @default.
• W2949642610 creator A5054719248 @default.
• W2949642610 creator A5086254380 @default.
• W2949642610 date "1998-12-01" @default.
• W2949642610 modified "2023-10-03" @default.
• W2949642610 title "Coordination chemistry of mononuclear iron carbonyl complexes" @default.
• W2949642610 cites W1523134656 @default.
• W2949642610 cites W1536389469 @default.
• W2949642610 cites W1550470940 @default.
• W2949642610 cites W1556952675 @default.
• W2949642610 cites W1594403992 @default.
• W2949642610 cites W1970570106 @default.
• W2949642610 cites W1975061804 @default.
• W2949642610 cites W1975861804 @default.
• W2949642610 cites W1977176675 @default.
• W2949642610 cites W1977744717 @default.
• W2949642610 cites W1979617258 @default.
• W2949642610 cites W1979679320 @default.
• W2949642610 cites W1980041763 @default.
• W2949642610 cites W1986170265 @default.
• W2949642610 cites W1986445682 @default.
• W2949642610 cites W1988537490 @default.
• W2949642610 cites W1991571907 @default.
• W2949642610 cites W1991847968 @default.
• W2949642610 cites W1992233141 @default.
• W2949642610 cites W2000946136 @default.
• W2949642610 cites W2003332882 @default.
• W2949642610 cites W2006723818 @default.
• W2949642610 cites W2017179930 @default.
• W2949642610 cites W2018674924 @default.
• W2949642610 cites W2019077191 @default.
• W2949642610 cites W2021434261 @default.
• W2949642610 cites W2032041953 @default.
• W2949642610 cites W2042026693 @default.
• W2949642610 cites W2048885077 @default.
• W2949642610 cites W2052397651 @default.
• W2949642610 cites W2054242321 @default.
• W2949642610 cites W2055047960 @default.
• W2949642610 cites W2058216462 @default.
• W2949642610 cites W2059834486 @default.
• W2949642610 cites W2064875148 @default.
• W2949642610 cites W2073159376 @default.
• W2949642610 cites W2076217943 @default.
• W2949642610 cites W2084137730 @default.
• W2949642610 cites W2084714485 @default.
• W2949642610 cites W2088204573 @default.
• W2949642610 cites W2089149620 @default.
• W2949642610 cites W2091702998 @default.
• W2949642610 cites W2093960175 @default.
• W2949642610 cites W2098147389 @default.
• W2949642610 cites W2210038565 @default.
• W2949642610 cites W2317925328 @default.
• W2949642610 cites W2476862745 @default.
• W2949642610 cites W2940709908 @default.
• W2949642610 cites W2949955871 @default.
• W2949642610 cites W2950494554 @default.
• W2949642610 cites W2953231280 @default.
• W2949642610 cites W3005199896 @default.
• W2949642610 cites W4250811699 @default.
• W2949642610 cites W4255436742 @default.
• W2949642610 doi "https://doi.org/10.1016/s0010-8545(98)00075-7" @default.
• W2949642610 hasPublicationYear "1998" @default.
• W2949642610 type Work @default.
• W2949642610 sameAs 2949642610 @default.
• W2949642610 citedByCount "14" @default.
• W2949642610 countsByYear W29496426102015 @default.
• W2949642610 countsByYear W29496426102016 @default.
• W2949642610 countsByYear W29496426102017 @default.
• W2949642610 countsByYear W29496426102018 @default.
• W2949642610 countsByYear W29496426102022 @default.
• W2949642610 crossrefType "journal-article" @default.
• W2949642610 hasAuthorship W2949642610A5007130170 @default.
• W2949642610 hasAuthorship W2949642610A5032595692 @default.
• W2949642610 hasAuthorship W2949642610A5033317919 @default.
• W2949642610 hasAuthorship W2949642610A5048169052 @default.
• W2949642610 hasAuthorship W2949642610A5054719248 @default.
• W2949642610 hasAuthorship W2949642610A5086254380 @default.
• W2949642610 hasConcept C111185830 @default.
• W2949642610 hasConcept C134018914 @default.
• W2949642610 hasConcept C155647269 @default.
• W2949642610 hasConcept C161790260 @default.
• W2949642610 hasConcept C178790620 @default.
• W2949642610 hasConcept C185592680 @default.
• W2949642610 hasConcept C201194858 @default.
• W2949642610 hasConcept C2777164566 @default.
• W2949642610 hasConcept C2778541603 @default.
• W2949642610 hasConcept C544153396 @default.
• W2949642610 hasConcept C68913812 @default.
• W2949642610 hasConcept C71240020 @default.
• W2949642610 hasConcept C71924100 @default.
• W2949642610 hasConceptScore W2949642610C111185830 @default.
• W2949642610 hasConceptScore W2949642610C134018914 @default.
• W2949642610 hasConceptScore W2949642610C155647269 @default.

• next