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- W2949643246 abstract "Treatment of 1-chlorovinyl p-tolyl sulfoxides, derived from various cyclic ketones and chloromethyl p-tolyl sulfoxide, with lithium enolate of carboxylic acid tert-butyl esters or N,N-dimethylacetamide gave adducts in high yields. The adducts were treated with ether solution of isopropylmagnesium chloride in dry toluene to give bicyclo[n.1.0]alkane derivatives having tert-butyl carboxylate or acetamide moiety on the bridgehead carbon in high to quantitative yields via magnesium carbenoid 1,3-CH insertion reaction. The 1,3-CH insertion reaction proved to be regioselective and stereospecific. The reaction mechanism and origin of the selectivity and specificity are discussed." @default.
- W2949643246 created "2019-06-27" @default.
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- W2949643246 date "2008-11-18" @default.
- W2949643246 modified "2023-09-24" @default.
- W2949643246 title "ChemInform Abstract: A Synthesis of Bicyclo[n.1.0]alkanes Having tert-Butyl Carboxylate or Acetamide Moiety via the Intramolecular 1,3-CH Insertion of Magnesium Carbenoids." @default.
- W2949643246 cites W2077080084 @default.
- W2949643246 doi "https://doi.org/10.1002/chin.200847068" @default.
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