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- W2949645156 abstract "Cyclooctatetraene (COT), the first 4nπ-electron system to be studied, adopts an inherently nonplanar tub-shaped geometry of D2d symmetry with alternating single and double bonds, and hence behaves as a nonaromatic polyene rather than an antiaromatic compound. Recently, however, considerable 8π-antiaromatic paratropicity has been shown to be generated in planar COT rings even with the bond alternated D4h structure. In this review, we highlight recent theoretical and experimental studies on the antiaromaticity of hypothetical and actual planar COT. In addition, theoretically predicted triplet aromaticity and stacked aromaticity of planar COT are also briefly described." @default.
- W2949645156 created "2019-06-27" @default.
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- W2949645156 date "2010-05-11" @default.
- W2949645156 modified "2023-09-24" @default.
- W2949645156 title "ChemInform Abstract: Recent Studies on the Aromaticity and Antiaromaticity of Planar Cyclooctatetraene" @default.
- W2949645156 cites W2167933415 @default.
- W2949645156 doi "https://doi.org/10.1002/chin.201019273" @default.
- W2949645156 hasPublicationYear "2010" @default.
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