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• W2949647029 abstract "The syntheses, structures, and characterization of three new mixed metal selenites, Al2(Se2O5)3, Ga2(Se2O5)3, and In2(Se2O5)3 are reported. Al2(Se2O5)3 and Ga2(Se2O5)3 are isostructural to Cr2(Se2O5)3 and crystallize in the monoclinic space group P21/n (No. 14) with a = 10.825(6) Å, b = 11.214(3) Å, c = 11.567(6) Å, and β = 94.92(3)° for Al2(Se2O5)3 and a = 10.901(6) Å, b = 11.367(3) Å, c = 11.682(3) Å, and β = 95.07(3)° for Ga2(Se2O5)3. The third material, In2(Se2O5)3, crystallizes in the non-centrosymmetric space group Pc (No. 7) with a = 11.1463(5) Å, b = 13.3210(6) Å, c = 9.7149(4) Å, β = 105.478(1)°, and Z = 4. Nonlinear optical measurements on In2(Se2O5)3 indicate the material has second harmonic generating properties, with an efficiency of approximately 10 times SiO2. Infrared and thermogravimetric analyses for all three compounds are also presented." @default.
• W2949647029 created "2019-06-27" @default.
• W2949647029 creator A5054799694 @default.
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• W2949647029 date "2002-04-02" @default.
• W2949647029 modified "2023-09-23" @default.
• W2949647029 title "New Selenites: Syntheses, Structures, and Characterization of Centrosymmetric Al₂(Se₂O₅)₃ and Ga₂(Se₂O₅)₃ and Non-centrosymmetric In₂(Se₂O₅)₃" @default.
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• W2949647029 doi "https://doi.org/10.1021/cm011694t" @default.
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