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- W2949653492 abstract "5-Azidoisoxazoles are prepared via displacement of a chlorine atom in 5-chloroisoxazoles with azide ion. These 5-azidoisoxazoles contain an unsaturated group (olefin, aldehyde, oxime or hydrazone) in the 4-position which participates during thermal decomposition of the azide. Two types of products are formed which are non-interconvertible: (i) bicyclic isoxazoles which result from direct attack of the azide or nitrene on the unsaturated group; (ii) monocyclic pyrroles and pyrazoles which result from ring opening followed by bond reorganization and subsequent ring closure. Mechanisms for the two discrete processes are discussed." @default.
- W2949653492 created "2019-06-27" @default.
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- W2949653492 date "2010-08-16" @default.
- W2949653492 modified "2023-09-27" @default.
- W2949653492 title "ChemInform Abstract: Rearrangements of 5-Azidoisoxazoles." @default.
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- W2949653492 doi "https://doi.org/10.1002/chin.199551057" @default.
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