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- W2949659831 abstract "Abstract We herein report the synthesis of a chiral phosphonium salt, {[(4 S )-4-methyl-2-oxo-1,3-oxazolidin-4-yl]methyl}(triphenyl)phosphonium iodide 13 to provide a new Wittig reagent for the general method of synthesizing α-substituted alaninol derivatives. Our method described here is widely applicable to reactions with various types of aldehyde to afford olefin products with high E -selectivity, enabling us to provide a new approach to the synthesis of chiral S1P 1 agonists including our key intermediates, and of the trace amine-associated receptor 1 (TAAR1) agonist." @default.
- W2949659831 created "2019-06-27" @default.
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- W2949659831 date "2014-08-01" @default.
- W2949659831 modified "2023-09-27" @default.
- W2949659831 title "Synthesis of a chiral phosphonium salt for the preparation of α-substituted alaninol derivatives" @default.
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- W2949659831 doi "https://doi.org/10.1016/j.tet.2014.05.086" @default.
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