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- W2949662908 abstract "The direct azidation of various heterocyclic β-ketoesters, lactones, and lactams is reported. By using tosylazide and an organic base such as l-proline or TBD, the direct α-insertion of azide into these substrates was achieved in moderate to good yields, without competitive deacylating diazo transfer. This procedure represents an interesting alternative to the usual two-step approach of α-halogenation and subsequent displacement with azide ion." @default.
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- W2949662908 date "2009-09-01" @default.
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- W2949662908 title "Azidation of β-carbonyl lactones and lactams" @default.
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- W2949662908 doi "https://doi.org/10.1016/j.tetlet.2009.07.039" @default.
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