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- W2949663709 abstract "Abstract The reaction between tetrahalogeno- ortho -benzoquinones (X 4 C 6 O 2 - o ; X Cl, Br) and diphenyl ditelluride gives the unusual tellurium(IV) derivatives [(X 4 C 6 O 2 )TeC 6 H 5 ] 2 O. Crystallographic studies show that tellurium is coordinated by a substituted catecholate, a phenyl group, and a bridging oxygen. The mechanism of the reaction probably involves initial formation of a semiquinone-tellurium- phenyl species, since ESR spectroscopy identifies the presence of o -semiquinone radicals. A similar reaction was observed with (C 6 H 5 ) 2 Te 2 and 3,5-di-tert-butyl- ortho -benzoquinone." @default.
- W2949663709 created "2019-06-27" @default.
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- W2949663709 date "2010-08-19" @default.
- W2949663709 modified "2023-09-22" @default.
- W2949663709 title "ChemInform Abstract: The Oxidation of Diphenyl Ditelluride by Substituted Orthobenzoquinones, and the Molecular Structure of ((Cl4C6O2)TeC6H5)2O." @default.
- W2949663709 cites W1995166327 @default.
- W2949663709 doi "https://doi.org/10.1002/chin.199411233" @default.
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