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- W2949665077 abstract "Abstract A convenient three-step route to 1,5-dimethyl-1,3-benzazaphosphole via Cu- or Pd-catalyzed phosphonylation of 2-iodo-4-methylaniline, reduction to 2-phosphino-4-methylaniline, and disproportionative cyclization with excess formaldehyde is reported. N-Methylbenzazaphospholes can be functionalized in the 2-position via α-CH-lithiation with tBuLi and are π-acidic σ2P-ligands." @default.
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- W2949665077 date "2012-09-01" @default.
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- W2949665077 title "σ2-P Ligands: convenient syntheses of N-methyl-1,3-benzazaphospholes" @default.
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- W2949665077 doi "https://doi.org/10.1016/j.tetlet.2012.07.037" @default.
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